The first photos were developed in mercury fumes
On a silvered copper plate, the camera leaves an image you cannot see. To make it appear, the plate is held over a cup of mercury heated to about 60-80 C; the vapour clings only where light struck, building a frosty silver-mercury amalgam. The result is a one-of-a-kind mirror with no negative - tilt it and the picture flips between positive and shadow. The process was announced in January 1839.