These vases were painted in fire, not pigment
The black and orange of an ancient Greek vase were never paint — they're the same clay slip fired three times in one kiln. Air let in at about 800°C turns the whole pot rusty red. The vents are sealed and green wood added at about 950°C, starving the oxygen until the slip fuses to glassy black. Then air is let back in as it cools, re-reddening the bare clay while the sealed slip stays black. Athenian potters mastered this 2,500 years ago; the recipe was lost and only puzzled back out in the 20th century.