The first mirrors were polished volcanic glass
Long before silvered glass, people saw themselves in stone. At Neolithic settlements in central Anatolia — Catalhoyuk and Canhasan — craftsmen ground discs of obsidian, black volcanic glass, into mirrors around 6000 BCE, smoothing them with sand and fat until they shone. They are the oldest manufactured mirrors known, and every example found so far comes from what is now Turkey.